The history

The history of the RO water purifier

3,500 years from settling mud with alum to pushing water backwards through a plastic skin in millions of Indian kitchens.

For thousands of years people cleaned water by letting mud settle, boiling it and pouring it through cloth and sand. Then cholera showed that clear water could still kill, and cities turned to sand filters, chlorine and ultraviolet light. Meanwhile scientists discovered osmosis, and in 1959 and 1960 a UCLA team with an Indian-born chemist learned to run it in reverse. Today the same idea turns seawater into city water and hangs on kitchen walls across India, along with new questions about the water it wastes.

3,500+
years
29
moments
8
people
11
places

1748

Osmosis observed

Jean-Antoine Nollet, France

1829

Filtered water for a whole city

James Simpson, Chelsea Waterworks, London

1877

Osmotic pressure measured

Wilhelm Pfeffer, Germany

1908

Continuous chlorination of a US city's water

John Leal and George Fuller, Jersey City, USA

1910 (widely cited)

UV disinfection of a city's drinking water

Marseille, France

1959–1960

Practical reverse osmosis membrane

Sidney Loeb and Srinivasa Sourirajan, UCLA

1965

RO plant making drinking water for a town

Coalinga, California, USA

1981

Thin-film composite RO membrane patent

John Cadotte, FilmTec, USA

1984

Household water purifier brand in India

Aquaguard, Eureka Forbes

c. 1500 BCE (reported)Settle, boil and strain

1500 BCE – 1800

Settle, boil and strain

No one knows about germs yet. People make water look and taste better by letting mud settle, boiling it, warming it in the sun and straining it through cloth, sand and gravel.

1500 BCE

c. 1500 BCE (reported)

Alum makes the mud sink

Ancient Egyptians (reported)Egypt

The US EPA's history of water treatment says Egyptians reportedly used alum as early as 1500 BCE. Alum makes tiny floating specks clump together and sink, so clear water can be poured off the top. Tomb pictures from about the 15th to 13th centuries BCE show water being settled and siphoned.

Why it mattered. Clumping and settling dirt is still the first step at many water works today.

400 BCE

c. 400 BCE

Hippocrates' sleeve

Hippocrates (attributed)Greece

The Greek doctor Hippocrates is said to have boiled water for his patients and then poured it through a cloth bag. The bag came to be called the Hippocratic sleeve. It caught the bits that made water cloudy and smelly.

Why it mattered. It is one of the earliest recorded water filters, a simple version of the first stage in a modern purifier.

300

c. 300 CE (older layers earlier)

Boil it, sun it, filter it

Sushruta Samhita (Sanskrit medical text)India

This Sanskrit medical text advises boiling water, warming it in the sun and filtering it through sand and coarse gravel. Old books often say it dates from 2000 BCE, but scholars now think it was put together over several centuries and finished around the 3rd or 4th century CE. In India the seeds of the clearing-nut tree (nirmali or kataka) have long been rubbed in water pots to make mud settle.

Why it mattered. It shows people in India were already treating drinking water with heat, sunlight and sand, long before anyone knew about germs.

1748 – 1910

The push of water

Scientists notice that water sneaks through thin skins towards salty or sugary liquid, and learn to measure how hard it pushes. They call it osmosis.

1748

Water sneaks through a pig's bladder

Jean-Antoine NolletParis, France

Abbé Nollet tied a piece of pig's bladder over a jar of spirits of wine (alcohol) and sank it in water. After a few hours the bladder bulged outwards. When he pricked it, liquid squirted up more than a foot.

Why it mattered. It was the first recorded observation of osmosis: water moving through a thin skin towards the stronger solution.

1877

Measuring the push

Wilhelm PfefferGermany

The botanist Wilhelm Pfeffer made a man-made membrane inside the wall of an unglazed clay pot. With sugar water inside and pure water outside, water flowed in and pushed up the pressure. He measured that pressure and found it grew with how much sugar there was.

Why it mattered. It was the first measurement of osmotic pressure, the push an RO purifier's pump must beat.

1886

1886 (Nobel Prize 1901)

A law for osmotic pressure

Jacobus van 't HoffAmsterdam, Netherlands

Using Pfeffer's numbers, the Dutch chemist Jacobus van 't Hoff showed that dissolved substances push on a membrane much like a gas pushes on a container. The more stuff dissolved, and the warmer it is, the bigger the push. In 1901 he won the very first Nobel Prize in Chemistry, partly for this work.

Why it mattered. His law tells engineers how hard they must push salty water to force it backwards through a membrane.

1800 – 1920

Clean water for cities

Growing cities fight cholera and typhoid with sand filters, a map of a deadly pump, chlorine and the first ultraviolet lamps.

1804

A filter for a whole town

John Gibb and Robert ThomPaisley, Scotland

John Gibb ran a bleaching works and needed clean water. He built a sand filter designed by the engineer Robert Thom, and sold his extra filtered water to the townspeople.

Why it mattered. It is the first recorded sand filter to supply water to the public.

1829

London gets filtered water

James Simpson, Chelsea Waterworks CompanyLondon, England

The engineer James Simpson built slow sand filter beds for the Chelsea Waterworks Company. River water trickled slowly down through sand and gravel, which caught dirt and, as we now know, many germs.

Why it mattered. It is often called the first treated public water supply in the world.

1852

1852 (filtering required from 1855)

The law says: filter it

Parliament of the United KingdomLondon, England

The Metropolis Water Act said that all of London's drinking water had to be effectually filtered from the end of 1855. Later laws added regular checks of what was in the water.

Why it mattered. It was one of the first laws anywhere to demand treated drinking water.

1854

The Broad Street pump

John SnowSoho, London, England

When cholera killed hundreds of people in Soho, the doctor John Snow marked each death on a map. The deaths clustered around one water pump on Broad Street. He persuaded the local officials to take the pump's handle off.

Why it mattered. It helped prove that dirty water spreads disease, the reason we purify drinking water at all.

1877

Sunlight kills germs

Arthur Downes and Thomas BluntLondon, England

Downes and Blunt left test tubes of a nutrient liquid in the sun and others in the shade. The ones in sunlight stayed free of microbes. The part of sunlight that did the killing turned out to be ultraviolet light.

Why it mattered. It is the discovery behind the UV lamp inside many home purifiers.

1887

c. 1887–1890

40,000 samples and a map of salt

Ellen Swallow RichardsMassachusetts, USA

Ellen Swallow Richards, the first woman admitted to MIT, tested about 40,000 water samples for the Massachusetts Board of Health. She drew a 'normal chlorine' map showing how much salt the water naturally had in each place. Extra salt pointed to sewage pollution.

Why it mattered. Her work led to the first water-quality standards in the United States.

1897

Chlorine for a whole town

Maidstone water supplyMaidstone, England

After an outbreak of typhoid, bleach containing chlorine was used to treat Maidstone's entire water supply. It was a temporary emergency measure.

Why it mattered. Maidstone is often named as the first town to have its whole supply treated with chlorine.

1908

26 September 1908

Chlorine every day

John L. Leal and George W. FullerJersey City, New Jersey, USA

The doctor John Leal and the engineer George Fuller set up a plant that added chlorine to Jersey City's water at the Boonton Reservoir, every day, all the time. It treated about 40 million gallons a day. Within a few years chlorinated water spread across America and typhoid deaths fell.

Why it mattered. It was the first continuous chlorination of a US city's drinking water, one of the great public health wins in history.

1910

1910 (widely cited)

A city cleaned by UV light

Marseille water worksMarseille, France

A few years after the mercury vapour lamp was invented, Marseille used ultraviolet lamps to disinfect city drinking water. It is widely cited as the first full-scale UV water treatment.

Why it mattered. It showed that light alone could make water safe, the same job the UV lamp does in a home purifier.

1950 – 1985

Turning osmosis around

Chemists build plastic skins thin and tough enough to push water the wrong way, out of salty water. Reverse osmosis leaves the lab and starts making drinking water.

1959

Salt stays behind

Charles Reid and E. J. BretonUniversity of Florida, USA

Reid and Breton showed that thin films of cellulose acetate, a kind of plastic, let water through but held back most of the salt. The trouble was that water crept through far too slowly to be useful.

Why it mattered. It proved that a plastic skin could desalt water, if only it could be made faster.

1960

1959–1960 (patent granted 1964)

A skin thin enough to work

Sidney Loeb and Srinivasa SourirajanUCLA, Los Angeles, USA

Loeb and the Indian-born chemist Srinivasa Sourirajan found a way to cast cellulose acetate so that it had a very thin, dense skin on top of a spongy support. Water flowed through far faster, and salt still stayed behind. Their patent was filed in 1960 and granted in 1964.

Why it mattered. This was the first practical reverse osmosis membrane, the ancestor of the one in every RO purifier.

1963

c. 1963

Rolling the membrane up

General AtomicsSan Diego, California, USA

Engineers at General Atomics rolled flat sheets of membrane and spacer mesh around a central tube, like a Swiss roll. Water pushed in along the outside and clean water spiralled into the tube.

Why it mattered. The spiral-wound element packs a large membrane into a small tube, and it is the shape of the RO cartridge in a home purifier.

1965

June 1965

A town drinks RO water

Sidney Loeb and the city of CoalingaCoalinga, California, USA

Coalinga's well water was too full of minerals to drink, so drinking water was brought in by railway tank cars. A small plant with Loeb's membranes began turning the salty well water into drinking water, about 5,000 gallons a day.

Why it mattered. It was the first reverse osmosis plant to make drinking water for a town.

1981

filed 1979, granted 7 July 1981

The thin-film composite membrane

John Cadotte, FilmTecMinneapolis, Minnesota, USA

John Cadotte made a new kind of membrane by letting two chemicals meet where water and oil touch. They react into a polyamide layer far thinner than a hair, right on top of a porous support. His patent reported over 99.3% salt rejection with high flow.

Why it mattered. Almost every RO membrane made today, at home or in giant plants, is a thin-film composite like his.

1984 – today

A purifier in every kitchen

In India, UV and then RO purifiers become ordinary kitchen appliances. Standards and courts start asking how much water they waste and when they are really needed.

1984

Aquaguard arrives

Eureka ForbesIndia

Eureka Forbes, a joint venture of Forbes & Company and Electrolux, launched its Aquaguard water purifiers. Families who had only boiled or cloth-filtered water now had a machine on the wall that filtered it and killed germs with ultraviolet light. Aquaguard became so common that many people use the name for any purifier.

Why it mattered. It created the home water purifier market in India.

1984

WHO's drinking water guidelines

World Health OrganizationGeneva, Switzerland

The World Health Organization published the first edition of its Guidelines for Drinking-water Quality. They give countries a science-based list of what can safely be in drinking water, from germs to chemicals.

Why it mattered. Many national standards, including India's, lean on these guidelines.

1999

March 1999

RO comes to Indian kitchens

Mahesh Gupta, KENT RO SystemsNoida, India

Mahesh Gupta, an engineer who studied at IIT Kanpur, started KENT RO Systems after his own children fell ill from contaminated water, according to the company. KENT sold home purifiers that used reverse osmosis, a technology then mostly found in factories and plants.

Why it mattered. Home RO purifiers spread fast in Indian cities where groundwater is hard or salty.

2012

2012 (first issued in the 1980s)

India's drinking water standard

Bureau of Indian StandardsNew Delhi, India

The latest version of IS 10500, India's drinking water specification, says the acceptable level of total dissolved solids (TDS) is 500 mg per litre. Up to 2,000 mg per litre is permitted when there is no better source.

Why it mattered. This 500 mg per litre line is the number most Indian arguments about RO come back to.

2015

2015 (updated 2023)

A standard for home RO

Bureau of Indian StandardsNew Delhi, India

BIS published IS 16240, the Indian Standard for reverse osmosis purifiers used at home. Purifiers certified under it are tested for things such as how well they clean water and how much of the input water they recover.

Why it mattered. It gave buyers a way to trust a purifier, and put water wastage into the rulebook.

2019

May 2019

Don't use RO where you don't need it

National Green TribunalNew Delhi, India

India's National Green Tribunal told the government to stop RO use where water already has less than 500 mg per litre of TDS. It asked that purifiers recover more than 60% of the water, aiming for 75%, and that the reject water be used for mopping, gardening or washing. A 2020 draft rule, later tribunal orders and a 2022 Supreme Court stay kept the debate going.

Why it mattered. It made the whole country ask how much water home purifiers throw away, and whether soft water really needs RO.

2000 – today

Cities drink the sea

Giant RO plants turn seawater into drinking water for millions, using far less energy than the first plants, but leaving salty brine behind.

2010

July 2010

Chennai drinks the Bay of Bengal

Chennai Metropolitan Water Supply and Sewerage BoardMinjur, near Chennai, India

The Minjur plant began turning seawater from the Bay of Bengal into 100 million litres of drinking water a day by reverse osmosis. A second 100 million litre plant at Nemmeli began in 2013. A much bigger 400 million litre plant at Perur is expected around 2027.

Why it mattered. Minjur was India's largest desalination plant when it opened, and it made seawater a real water source for an Indian city.

2013

October 2013

Sorek, a giant by the sea

IDE TechnologiesSorek, south of Tel Aviv, Israel

The Sorek plant opened with a capacity of 624,000 cubic metres of drinking water a day, making it the world's biggest seawater RO plant at the time. It stacks huge 16-inch membrane tubes upright to save space.

Why it mattered. It showed seawater RO could supply a large share of a whole country's tap water.

2019

A thirsty world counts its plants

Edward Jones and colleagues (UN University)Worldwide

A study counted 15,906 working desalination plants making about 95 million cubic metres of fresh water a day, almost half of it in the Middle East and North Africa. It also found they make about 142 million cubic metres of salty brine a day.

Why it mattered. It showed that the waste stream, not just the clean water, is a big part of the desalination story.

By the numbers

Energy needed to make seawater drinkable with RO

Better membranes and devices that recycle pressure cut the electricity needed for each cubic metre (1,000 litres) of fresh water from the sea. Physics sets a floor of about 1 kWh per m³.

0 kWh per m³5 kWh per m³10 kWh per m³15 kWh per m³20 kWh per m³ 1975198019851990199520002005201020152020 1975: 1970s: around 20 kWh/m³ (Kumar, Culp and Shen, NAE 2017, as charted by Hannah Ritchie)19752011: 2011: state of the art 2.5 to 4 kWh/m³, midpoint shown (Elimelech and Phillip, Science)20112021: 2021: the most efficient plants use under 2 kWh/m³ (Danfoss)2021
  1. 1975 1970s: around 20 kWh/m³ (Kumar, Culp and Shen, NAE 2017, as charted by Hannah Ritchie)
  2. 2011 2011: state of the art 2.5 to 4 kWh/m³, midpoint shown (Elimelech and Phillip, Science)
  3. 2021 2021: the most efficient plants use under 2 kWh/m³ (Danfoss)

Did you know?

Sidney Loeb earned about $14,000 from the RO patent over its whole life, for an invention that grew into a multi-billion dollar industry.

Many older home RO purifiers kept only about 1 litre in 5 of the water that went in; the rest went down the drain as reject water.

Desalination plants around the world make more salty brine each day, about 142 million cubic metres, than fresh water, about 95 million.

Pulling the salt out of seawater needs at least about 1 kWh per cubic metre, a limit set by physics, and the best plants now use less than twice that.

When Nollet pricked his bulging pig's bladder in 1748, the liquid squirted up more than a foot.

The people

Who figured it out

Jean-Antoine Nollet

1700 – 1770 · Physicist and priest · France

The first person known to record osmosis, using a pig's bladder and a jar of alcohol.

Wilhelm Pfeffer

1845 – 1920 · Botanist · Germany

Built a membrane inside a clay pot and measured osmotic pressure for the first time.

Jacobus van 't Hoff

1852 – 1911 · Chemist · Netherlands

Wrote the law of osmotic pressure and won the first Nobel Prize in Chemistry.

John Snow

1813 – 1858 · Doctor · England

Mapped cholera deaths around the Broad Street pump and showed disease could spread through water.

Ellen Swallow Richards

1842 – 1911 · Chemist · USA

The first woman at MIT, whose huge water survey led to America's first water-quality standards.

John L. Leal

1858 – 1914 · Doctor and health officer · USA

Put chlorine into a US city's water every day, starting in Jersey City in 1908.

Sidney Loeb

1917 – 2008 · Chemical engineer · USA and Israel

Co-invented the first practical RO membrane, then moved to Israel and invented pressure retarded osmosis.

Srinivasa Sourirajan

1923 – 2022 · Chemist and chemical engineer · India and Canada

Born in Tamil Nadu, he co-invented the RO membrane at UCLA and later made Canada's National Research Council a world centre for membrane research.

Where it happened

11 places, one idea

Sources

Where this comes from

Dates marked “c.” are approximate, and historians sometimes disagree about who was first. If you spot a mistake, tell us.

  1. Water purification Wikipedia
  2. The History of Drinking Water Treatment (EPA-816-F-00-006, February 2000) U.S. Environmental Protection Agency
  3. History of water filters Wikipedia
  4. Sushruta Samhita Wikipedia
  5. Strychnos potatorum (clearing-nut tree) Wikipedia
  6. Slow sand filter Wikipedia
  7. John Snow Wikipedia
  8. John Snow site UCLA Fielding School of Public Health
  9. John L. Leal Wikipedia
  10. History of municipal treatment of drinking water Wikipedia
  11. Ultraviolet germicidal irradiation Wikipedia
  12. The History of Ultraviolet Germicidal Irradiation for Air Disinfection (Reed, 2010) Public Health Reports, via PubMed Central
  13. Jean-Antoine Nollet Wikipedia
  14. Osmosis Encyclopaedia Britannica
  15. Pfeffer Cell Apparatus Embryo Project Encyclopedia, Arizona State University
  16. The Nobel Prize in Chemistry 1901: Jacobus H. van 't Hoff NobelPrize.org
  17. Reverse osmosis Wikipedia
  18. Water Desalination: History, Advances, and Challenges (Kumar, Culp and Shen, 2017) National Academy of Engineering, National Academies Press
  19. Sidney Loeb Wikipedia
  20. US 3,133,132: High flow porous membranes for separating water from saline solutions Google Patents
  21. Remembering Srinivasa Sourirajan, the 'father of reverse osmosis' Shaastra, IIT Madras
  22. Water Warriors UCLA Magazine
  23. US 4,277,344: Interfacially synthesized reverse osmosis membrane Google Patents
  24. Sorek I Desalination Plant IDE Technologies
  25. Minjur Seawater Desalination Plant Wikipedia
  26. Nemmeli Seawater Desalination Plant Wikipedia
  27. Perur desalination plant to add 400 MLD to Chennai's water supply by 2027 DT Next
  28. Eureka Forbes Wikipedia
  29. Eureka Forbes: The Water Wars (case study) ICMR India
  30. About KENT RO Systems KENT RO Systems
  31. NGT: Ban ROs where dissolved solids in water below 500 mg/l The Tribune
  32. Centre's new draft for RO systems not what NGT asked for Down To Earth
  33. SC stays NGT ban on water purifiers where TDS below 500 mg per litre Business Standard
  34. Product manual for IS 10500: Drinking water, specification Bureau of Indian Standards
  35. Product manual for IS 16240: Reverse osmosis based point-of-use water treatment system Bureau of Indian Standards
  36. The state of desalination and brine production: A global outlook (Jones et al., 2019) Science of the Total Environment
  37. The Future of Seawater Desalination: Energy, Technology, and the Environment (Elimelech and Phillip, 2011) Science
  38. How much energy does desalinisation use? Hannah Ritchie, Sustainability by Numbers
  39. A brief history of the energy intensity of desalination Danfoss
  40. Ellen Swallow Richards Wikipedia
  41. Guidelines for drinking-water quality World Health Organization
  42. Jacobus Henricus van 't Hoff Wikipedia

That's the history. Now see how it works.